Journal of Liaoning Petrochemical University
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Preparation and Property on Cyclohexane  Dehydrogenation Activity of Mo2C/CCA
LIU Zhao, MA Jun, WANG Hai-yan,BAI Ying-zhi, LIU Lu
Abstract296)      PDF (281KB)(347)      
The Mo3O/CCA was prepared by impregnation method using the (NH4)6Mo7O24·4H2O as the molybdenum source, carbon covered γ-Al2O3 (CCA) as support, and n-hexane as the carbon source. After carbonization of Mo3O/CCA obtained Mo2C/CCA. The catalysts prepared at different carbonization temperature were characterized by XRD. The effects of preparation and reaction conditions on dehydrogenation activity of the catalyst were studied in a fixed-bed down-flow reactor. The results show that the conversion of cyclohexane up to 91% was attained under the optimum condition as follows: CCA carbon covered 7.82%, final carbonization temperature 650 ℃, reaction temperature 475 ℃, reaction pressure 0.1 MPa, liquid hourly space velocity 2 h-1 and volume ratio of hydrogen to cyclohexane 200∶1.
2012, 32 (3): 13-16.
The Preparation of Hydrodenitrogenation Activity of the MoP/TiO 2-SiO 2-Al 2O 3
JIANG Xu,GU Yong-he,WANG Hai-yan*,WEI Min,BAI Ying-zhi,MA Jun
Abstract369)      PDF (260KB)(265)      
 
The TiO 2-SiO 2-Al 2O 3 composite support was prepared by sol-gel method, and then the MoP/TiO 2-SiO 2-Al 2O 3 catalyst was prepared in the way of co-impregnation. XRD results show that the diffraction peaks of TiO 2 crystalline phase is due to anatase and SiO 2 is mostly amorphous dispersed in γ-Al 2O 3 cystal surface. After in-situ reduction, the hydrodearomatization (HDA) activity of the catalyst was investigated in the fixed bed reactor. The results suggest that the mole ratio of Ti, Si and Al have a great influence on the activity of composite support catalyst. HDA activity of the MoP/TiO 2-SiO 2-Al 2O 3 catalyst shows the highest activity (65.6%) when the ratio of n(Ti)∶n(Si)∶n(Al) was 1∶1∶4, the Mo loading amount is 20%. In addition, the results also show that the HDA rate of the catalyst with the composite TiO 2-SiO 2-Al 2O 3 support was 19.6% and 13.6% higher than the traditional cataslysts of γ-Al 2O 3 and SiO 2-Al 2O 3, respectively.
2010, 30 (3): 24-27. DOI: 10.3696/j.issn.1672-6952.2010.03.007
Serviceability of SBS Modified Paving Asphalt From Tahe Crude Oil
FU Li, WANG Hai -y an, MA Jun
Abstract234)      PDF (322KB)(328)      
        The SBS modified paving asphalt was developed from the Tahe crude oil containing more asphaltine .The problem about compatibility and storage stability between SBS polymer and the base asphalt were solved by adding compatilizer and stabilizer .This SBS modified paving asphalt which was up to JTG F40 -2004 technical specifications was evaluated by conventional test method and SHRP test method and compared with other SBS modified paving asphalt .The results show that the penetration index of SBS modified paving asphalt from the Tahe crude oil is more than 1 , the viscous -elastic range is 93.06 ℃, its equivalent softening point is 58 .08 ℃ and its equivalent break point is -34 .98 ℃ by conventional test method.So it has very small temperature sensitivity , wider viscous-elastic range and excellent high -low temperature performance .This kind o f SBS modified paving asphalt is applied in wider temperature range .I ts performance grade evaluated by SHRP test method reaches PG76 -34 .The performance grade of others compared SBS modified paving asphalt is PG70 -28.These results show SBS modified paving asphalt from the Tahe crude oil possesses excellent serviceability
2005, 25 (3): 20-23.
Effect of Car rier Activation on Etherif ication Activity of PW 12/Carbonized Resin Catalyst
WEI Min,WANG Hai -yan,MA Jun,BAI Ying -zhi
Abstract368)      PDF (212KB)(413)      
        The carbonized resin w as prepared using strong acid cation exchange resin as the precursor .Using the carbonized resin as carrier , the carbonized resin supported PW 12 catalyst was prepared by loading PW 12 on the carbonized resin .Effect of activation condition of the carbonized resin on the surface performance, loadings of PW 12and stability of PW 12 were investigated.The adsorption process of solid acid catalyst PW 12 on carbonized resin w as influenced.Research results show that activation of HNO 3 is better than that of HCl, H 2SO 4 and H 3PO 4 , and the optimal concentration of HNO 3 of the pretreatment solution is 4.5mol/L .The etherification of light catalytic cracking gasoline and methanol w as carried out under the conditions of reaction temperature is 70 ℃,methanol and olefin mole ratio is 1.1, pressure is 1 .0 MPa , LHSV is 1.0 h-1 .The conversion of tertiary carbonic olefin is up to 56.68 %, which is higher than that of D005 strong acid cation exchange resin catalyst.
2005, 25 (1): 52-54.